Following its gains on the ground, Russia sent a delegation to Belarus for peace talks with Ukraine, according to the Kremlin. Ukraine's president suggested other locations, saying his country was unwilling to meet in Belarus because it served as a staging ground for the invasion.
Until Sunday, Russia's troops had remained on the outskirts of Kharkiv, a city of 1.4 million about 20 kilometers (12.4 miles) south of the border with Russia, while other forces rolled past to press the offensive deeper into Ukraine.
Videos posted on Ukrainian media and social networks showed Russian vehicles moving across Kharkiv and Russian troops roaming the city in small groups. One showed Ukrainian troops firing at the Russians and damaged Russian light utility vehicles abandoned nearby.
The images underscored the determined resistance Russian troops face while attempting to enter Ukraine's bigger cities. Ukrainians have volunteered en masse to help defend the capital, Kyiv, and other cities, taking guns distributed by authorities and preparing firebombs to fight Russian forces.
Ukraine's government also is releasing prisoners with military experience who want to fight for the country, a prosecutor's office official, Andriy Sinyuk, told the Hromadske TV channel Sunday. He did not specify whether the move applied to prisoners convicted of all levels of crimes.
``We are fighting, fighting for our country, fighting for our freedom because we have the right to do that,'' Ukrainian President Volodymyr Zelenskyy said. ``The past night was tough _ more shelling, more bombing of residential areas and civilian infrastructure. There is not a single facility in the country that the occupiers wouldn't consider as admissible targets.''
Huge explosions lit up the sky early Sunday near Kyiv, where terrified residents hunkered down in homes, underground garages and subway stations in anticipation of a full-scale Russian assault.
A 39-hour curfew to keep people off the capital's streets until Monday morning complicated the task of assessing the intensity of the fighting. Zelenskyy's office said explosions were reported at Kyiv International Airport.
Flames billowed from an oil depot near an airbase in Vasylkiv, a city 37 kilometers (23 miles) south of Kyiv where there has been intense fighting, according to the mayor. Russian forces blew up a gas pipeline to the east in Kharkiv, prompting the government to warn people to cover their windows with damp cloth or gauze as protection from smoke, the president's office said.
Russian President Vladimir Putin hasn't disclosed his ultimate plans, but Western officials believe he is determined to overthrow Ukraine's government and replace it with a regime of his own, redrawing the map of Europe and reviving Moscow's Cold War-era influence.
The pressure on strategic ports in the south of Ukraine appeared aimed at seizing control of the country's coastline stretching from the border with Romania in the west to the border with Russia in the east. A Russian Defense Ministry spokesman, Maj. Gen. Igor Konashenkov, said Russian forces had blocked the cities of Kherson on the Black Sea and the port of Berdyansk on the Azov Sea.
He said the Russian forces also took control of an airbase near Kherson and the Azov Sea city of Henichesk. Ukrainian authorities also have reported fighting near Odesa, Mykolaiv and other areas.
Cutting Ukraine's access to its sea ports would deal a major blow to the country's economy. It also could allow Moscow to build a land corridor to Crimea, which Moscow annexed in 2014 and until now was connected to Russia by a 19-kilometer (12-mile) bridge, the longest bridge in Europe which opened in 2018.
The number of casualties so far from Europe's largest land conflict conflict since World War II remain unclear amid the fog of combat.
Ukraine's health minister reported Saturday that 198 people, including three children, had been killed and more than 1,000 others wounded. It was unclear whether those figures included both military and civilian casualties. Russia has not released any casualty information.
Ukraine's U.N. ambassador, Sergiy Kyslytsya, tweeted Saturday that Ukraine appealed to the International Committee of the Red Cross ``to facilitate repatriation of thousands of bodies of Russian soldiers.'' An accompanying chart claimed 3,500 Russian troops have been killed.
Laetitia Courtois, ICRC's permanent observer to the U.N., told The Associated Press that the situation in Ukraine was ``a limitation for our teams on the ground'' and ``we therefore cannot confirm numbers or other details.''
The United Nations' refugee agency said late Saturday more than 200,000 Ukrainians have arrived in neighboring countries since the invasion started Thursday. The U.N. has estimated the conflict could produce as many as 4 million refugees, depending how long it continues.
Zelenskyy denounced Russia's offensive as ``state terrorism.'' He said the attacks on Ukrainian cities should be investigated by an international war crimes tribunal and cost Russia its place as one of the five permanent members of the United Nations Security Council.
``Russia has taken the path of evil, and the world should come to depriving it of its U.N. Security Council seat,'' he said.
Kremlin spokesman Dmitry Peskov said a Russian delegation of military officials and diplomats had arrived Sunday in the Belarusian city of Gomel for talks with Ukraine. Zelenskyy on Friday offered to negotiate a key Russian demand: abandoning ambitions of joining NATO.
Ukraine's president said his country was ready for peace talks but not in Belarus.
``Warsaw, Bratislava, Budapest, Istanbul, Baku, we offered all of them to the Russian side and we will accept any other city in a country that hasn't been used for launching missiles,`` Zelenskyy said. ``Only then the talks could be honest and put an end to the war.''
Peskov claimed Ukraine had proposed holding talks in Gomel. He added that the Russian military action was going forward pending the talks start.
Zelenskyy adviser Mykhailo Podolyak dismissed Moscow's offer as ``manipulation,'' adding that Ukraine hadn't agreed to talks in the Belarusian city.
As Russia pushes ahead with its offensive, the West is working to equip the outnumbered Ukrainian forces with weapons and ammunition while punishing Russia with far-reaching sanctions intended to further isolate Moscow.
The U.S. pledged an additional $350 million in military assistance to Ukraine, including anti-tank weapons, body armor and small arms. Germany said it would send missiles and anti-tank weapons to the besieged country and that it would close its airspace to Russian planes.
The U.S., European Union and United Kingdom agreed to block ``selected'' Russian banks from the SWIFT global financial messaging system, which moves money around more than 11,000 banks and other financial institutions worldwide, part of a new round of sanctions aiming to impose a severe cost on Moscow for the invasion. They also agreed to impose ''restrictive measures'' on Russia's central bank.
Responding to a request from Ukraine's minister of digital transformation, tech billionaire Elon Musk said on Twitter that his satellite-based internet system Starlink was now active in Ukraine and that there were ``more terminals en route.''
German Chancellor Olaf Scholz, meanwhile, said Sunday that his country is committing 100 billion euros ($112.7 billion) to a special fund for its armed forces, raising its defense spending above 2% of gross domestic product. Scholz told a special session of the Bundestag the investment was needed ``to protect our freedom and our democracy.''
Putin sent troops into Ukraine after denying for weeks that he intended to do so, all the while building up a force of almost 200,000 troops along the countries' borders. He claims the West has failed to take seriously Russia's security concerns about NATO, the Western military alliance that Ukraine aspires to join. But he has also expressed scorn about Ukraine's right to exist as an independent state.
Russia claims its assault on Ukraine is aimed only at military targets, but bridges, schools and residential neighborhoods have been hit.
Ukraine's ambassador to the U.S., Oksana Markarova, said Ukraine was gathering evidence of shelling of residential areas, kindergartens and hospitals to submit to an international war crimes court in The Hague as possible crimes against humanity. The International Criminal Court's prosecutor has said he is monitoring the conflict closely.
British Foreign Secretary Liz Truss warned Sunday that Putin could use ``the most unsavory means,'' including banned chemical or biological weapons, to defeat Ukraine.
``I urge the Russians not to escalate this conflict, but we do need to be prepared for Russia to seek to use even worse weapons,'' Truss told Sky News.